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Maxwell–Boltzmann statistics : ウィキペディア英語版
Maxwell–Boltzmann statistics

In statistical mechanics, Maxwell–Boltzmann statistics describes the average distribution of non-interacting material particles over various energy states in thermal equilibrium, and is applicable when the temperature is high enough or the particle density is low enough to render quantum effects negligible.
The expected number of particles with energy \varepsilon_i for Maxwell–Boltzmann statistics is \langle N_i \rangle where:
:
\langle N_i \rangle = \frac \,g_i e^

where:
*\varepsilon_i is the ''i''-th energy level
*\langle N_i \rangle is the number of particles in the set of states with energy \varepsilon_i
*g_i is the degeneracy of energy level ''i'', that is the number of single-particle states with energy \varepsilon_i
*μ is the chemical potential
*''k'' is Boltzmann's constant
*''T'' is absolute temperature
*''N'' is the total number of particles
::N=\sum_i N_i\,
*''Z'' is the partition function
::Z=\sum_i g_i e^
*e(...) is the exponential function
Equivalently, the particle number is sometimes expressed as
:
\langle N_i \rangle = \frac \,e^

where the index ''i''  now specifies a particular state rather than the set of all states with energy \varepsilon_i, and Z=\sum_i e^
==Applications==

Maxwell–Boltzmann statistics may be used to derive the Maxwell–Boltzmann distribution (for an ideal gas of classical particles in a three-dimensional box). However, they apply to other situations as well. Maxwell–Boltzmann statistics can be used to extend that distribution to particles with a different energy–momentum relation, such as relativistic particles (Maxwell–Jüttner distribution). In addition, hypothetical situations can be considered, such as particles in a box with different numbers of dimensions (four-dimensional, two-dimensional, etc.).

抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
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